We develop chiral perturbation theory for chirally broken theories with fermions in two different representations of the gauge group. Any such theory has a nonanomalous singlet U(1)A symmetry, yielding an additional Nambu-Goldstone boson when spontaneously broken. We calculate the next-to-leading order corrections for the pseudoscalar masses and decay constants, which include the singlet Nambu-Goldstone boson, as well as for the two condensates. The results can be generalized to more than two representations.